Sodium-Ion 18650 Test Report v1: NFPP and Layered Oxide vs LFP

Sodium-Ion 18650 Test Report v1: NFPP and Layered Oxide vs LFP

OGS bench test · report v1

We put two sodium-ion 18650 cells and an LFP 18650 on our battery tester and ran each one through a full charge and discharge at about 0.5C, at room temperature.

All three cells delivered within about 5% of their rated capacity, and every bit of charge we put in came back out. The more useful part for builders is the shape of the curves: they explain why sodium-ion needs different BMS and inverter settings from LFP.

851 mAh
NFPP at 0.5C (rated 900)
1,216 mAh
Layered oxide at 0.5C (rated 1,300)
≈100%
charge in = charge out
3
chemistries, same test
The test

What we tested and how

Each cell was charged with the standard method from its datasheet: constant current until it reached its top voltage, then held at that voltage until the current fell to 0.1 A. After a short rest we discharged it at a constant current to its rated cutoff voltage. Room temperature, one cell at a time, on a ZKETECH EBC-A20 tester.

NFPP
Sodium-ion NFPP
Phosphate cathode, the sodium cousin of LFP. 3.0 V nominal, 1.5–3.7 V window.
Layered oxide
Sodium-ion layered oxide
Layered metal-oxide cathode. 3.05 V nominal, 1.8–3.95 V window on this batch.
Reference
LFP (LiFePO₄)
A 1,500 mAh lithium iron phosphate 18650, included as the familiar reference.

The sodium cells here are earlier batches (900 mAh NFPP and 1,300 mAh layered oxide). The cells we stock now are the 850 mAh NFPP and 1,100 mAh layered oxide; they are next on the bench.

Results

Capacity at about 0.5C

Cell Window Current Capacity Of rating Energy
Sodium-ion NFPP
Rated 900 mAh (earlier batch)
3.70 → 1.50 V 0.45 A 851 mAh 95% 2.34 Wh
Sodium-ion layered oxide
Rated 1,300 mAh (earlier batch)
3.95 → 1.80 V 0.65 A 1,216 mAh 94% 3.51 Wh
LFP (lithium reference)
Rated 1,500 mAh
3.65 → 2.50 V 1.00 A 1,446 mAh 96% 4.15 Wh

Manufacturers rate capacity at a gentler 0.2C, so landing at 94–96% at 0.5C is normal. Each cell gave a little more when we continued at lower currents after the cutoff (another 35–155 mAh). Charge in matched charge out within 1–2% for all three.

Discharge voltage versus capacity for NFPP, layered oxide and LFP 18650 cells at about 0.5C

Discharge voltage under load vs capacity delivered.

Curve shape

Three very different voltage curves

Scaling each curve to its own capacity shows the real difference between the chemistries. This is what your BMS, inverter and battery monitor will see.

Discharge curves scaled to percent of capacity for NFPP, layered oxide and LFP

Same discharges, plotted against depth of discharge.

LFP
Nearly flat
LFP holds an almost constant voltage from 5% to 85% discharged, then drops off sharply. Steady output, but voltage tells you very little about how full it is.
NFPP
Plateau, then slope
NFPP settles onto a flat ~3.0 V plateau for the first ~40%, then slopes down steadily. Between those two shapes.
Layered oxide
Steady slope
Layered oxide falls in a near-straight line from 3.7 V to 1.8 V. Voltage maps cleanly to state of charge, which makes simple voltage-based fuel gauges work well.
Charging

How each cell charges

Charge voltage versus charge put in for NFPP, layered oxide and LFP 18650 cells

Constant-current, constant-voltage charge from empty, ending at 0.1 A.

  • NFPP climbs to a plateau near 3.3 V, then rises steeply to 3.7 V in the last few percent. That sharp rise is an easy end-of-charge signal for a charger or BMS.
  • Layered oxide rises almost in a straight line all the way to 3.95 V.
  • LFP jumps quickly and spends most of its charge at the 3.65 V limit. Part of that early jump comes from our test leads (see below).
For your build

What this means for your pack

Set the low cutoff with care
On both sodium cells about 15–20% of the capacity sits below 2.5 V, but only 3–5% sits below 2.0 V. A per-cell cutoff around 2.0–2.2 V keeps nearly all of it with margin above the datasheet floor. A 2.5 V cutoff gives up about a fifth.
Check your inverter's window
Sodium cells swing over a much wider voltage range than LFP. A 16-cell layered-oxide pack runs from roughly 25A 16-cell layered-oxide pack spans about 29 V to 63 V, so comparendash;30 V when empty to about 63 V when full, so compare the full range, not just the nominal voltage, with what your inverter accepts.
Use a sodium BMS profile
Lithium and LFP presets have the wrong limits in both directions. Use a programmable BMS and set it to the datasheet values for the exact cells and batch you have.
About these numbers

How to read this test

  • The tester read voltage through its test leads and cell holder, which added roughly 0.3 Ω to the circuit. At 0.5–1 A that makes every voltage read about 0.15–0.35 V lower than the cell itself, and makes each cell reach its cutoff a little early. The capacities above are therefore slightly conservative.
  • The energy figures are measured under load with the same lead loss, so they understate what the cells deliver in a well-built pack.
  • The LFP cell was discharged at 1.0 A (about 0.67C) instead of exactly 0.5C.
  • One cell of each type, one cycle each. This is a bench check, not a cycle-life study.
Coming next

Test report v2

Next we test the cells we stock today, the 850 mAh NFPP and the 1,100 mAh layered oxide, at 0.5C and room temperature. We will use a 4-wire holder that measures voltage right at the cell terminals.

They will go on the same charts as the cells above, so you can compare all five side by side.

In stock at OGS
NFPP Sodium-Ion 18650, 850 mAh, 40C high-rate
NFPP Sodium-Ion 18650
850 mAh, 40C high-rate
Layered Oxide Sodium-Ion 18650, 1,100 mAh
Layered Oxide Sodium-Ion 18650
1,100 mAh

Results are from our own bench tests on individual cells and can vary between cells and batches. Always set pack limits from the datasheet for the cells you actually have. Related: NFPP 18650 review · Layered oxide 18650 review

Back to blog